Thermo Scientific Chemicals

Dodecacarbonyltriruthenium, 99%, Thermo Scientific Chemicals

Catalog number: 010507.06
5 g, Each
Thermo Scientific Chemicals

Dodecacarbonyltriruthenium, 99%, Thermo Scientific Chemicals

Catalog number: 010507.06
5 g, Each
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Catalog number: 010507.06
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Quantity
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Chemical Identifiers

CAS
15243-33-1
IUPAC Name
cyclotriruthenium; dodecakis(methanidylidyneoxidanium)
Molecular Formula
C12O12Ru3
InChI Key
NQZFAUXPNWSLBI-UHFFFAOYSA-N
SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1
Assay (unspecified)
99% min

Description

A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

RUO – Research Use Only

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