1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, Thermo Scientific Chemicals
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, Thermo Scientific Chemicals

 
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Quantity:
250 mg
Catalog number 042057.MD
also known as 042057-MD
Price (USD)/ Each
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Quantity:
250 mg
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Chemical Identifiers
CAS64536-78-3
IUPAC Nameiridium(1+) (1Z,5Z)-cycloocta-1,5-diene hexafluoro-λ⁵-phosphanuide pyridine tricyclohexylphosphane
Molecular FormulaC31H50F6IrNP2
InChI KeyUJXHUUQZACSUOG-KJWGIZLLSA-N
SMILES[Ir+].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
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SpecificationsSpecification SheetSpecification Sheet
FormPowder
Phosphorus-31 NMRTo conform to structure
Appearance (Color)Orange
Elemental AnalysisCarbon C: 45.3 - 47.3%
Elemental AnalysisNitrogen N: 1.2 - 2.2%
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1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

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