Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I), Thermo Scientific Chemicals
Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I), Thermo Scientific Chemicals
Thermo Scientific Chemicals

Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I), Thermo Scientific Chemicals

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2 g
Catalog number 044446.02
also known as 044446-02
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262.65
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Quantity:
0.5 g
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Price (USD)/ Each
262.65
Online exclusive
292.00 
Save 29.35 (10%)
Add to cart
Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I), Thermo Scientific Chemicals
Catalog number044446.02
Price (USD)/ Each
262.65
Online exclusive
292.00 
Save 29.35 (10%)
-
Add to cart
Chemical Identifiers
CAS185812-86-6
IUPAC Namebis(tri-tert-butyl-λ⁵-phosphanyl)cyclodipalladabromane
Molecular FormulaC24H56Br2P2Pd2
InChI KeyJWWUTWDBVLEWDQ-UHFFFAOYSA-P
SMILESCC(C)(C)P([Pd]1[Br][Pd]([Br]1)P(C(C)(C)C)(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C
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SpecificationsSpecification SheetSpecification Sheet
FormCrystals or crystalline powder
Phosphorus-31 NMRConforms to structure
Appearance (Color)Dark green or greenish-blue
Proton NMRConforms to structure
Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Coupling reactions
  • Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides
  • Especially active in difficult aminations
RUO – Research Use Only