4,4'-Bipyridine is used in transition-metal complex catalyst chemistry for uniform polymerization, in luminescence chemistry and in spectrophotometric analysis. It plays an important role as a photosensitizer and luminescent material. It is also used as a precursor to paraquat viz. N,N'-dimethyl-4,4'-bipyridinium.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4,4′-Bipyridine is used in transition-metal complex catalyst chemistry for uniform polymerization, in luminescence chemistry and in spectrophotometric analysis. It plays an important role as a photosensitizer and luminescent material. It is also used as a precursor to paraquat viz. N,N′-dimethyl-4,4′-bipyridinium.
Solubility
Soluble in ethanol, ether. Insoluble in water.
Notes
Incompatible with strong oxidizing agents and strong acids.
RUO – Research Use Only
General References:
- Ohmura, T.; Morimasa, Y.; Suginome, M. Organocatalytic Diboration Involving Reductive Addition of a Boron-Boron σ-Bond to 4,4'-Bipyridine. J. Am. Chem. Soc. 2015, 137 (8), 2852-2855.
- Aniola, M.; Katrusiak, A. Conformational Conversion of 4,4'-Bipyridinium in a Hidden High-Pressure Phase. Cryst. Growth Des. 2015, 15 (2), 764-770.