Hexamethylbenzene, 99+%, Thermo Scientific Chemicals
Hexamethylbenzene, 99+%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Hexamethylbenzene, 99+%, Thermo Scientific Chemicals

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25 g
Catalog number A10294.03
also known as A10294-03
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Hexamethylbenzene, 99+%, Thermo Scientific Chemicals
Catalog numberA10294.03
Price (USD)/ Each
31.70
-
Add to cart
Chemical Identifiers
CAS87-85-4
IUPAC Namehexamethylbenzene
Molecular FormulaC12H18
InChI KeyYUWFEBAXEOLKSG-UHFFFAOYSA-N
SMILESCC1=C(C)C(C)=C(C)C(C)=C1C
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SpecificationsSpecification SheetSpecification Sheet
FormCrystals or powder or crystalline powder or flakes
Identification (FTIR)Conforms
Melting Point161.5-167.5?C
Appearance (Color)White to pale yellow
Assay (GC)≥99.0%
Hexamethylbenzene is used as pharmaceutical intermediates, in organic synthesis of compounds, as a solvent for He-NMR spectroscopy. Used as a ligand in organometallic chemistry. Reaction with dimethyldioxirane, gives the major product, an unusual oxepane triepoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexamethylbenzene is used as pharmaceutical intermediates, in organic synthesis of compounds, as a solvent for He-NMR spectroscopy. Used as a ligand in organometallic chemistry. Reaction with dimethyldioxirane, gives the major product, an unusual oxepane triepoxide.

Solubility
Insoluble in water

Notes
Incompatible with nitromethane, strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Helena L. Chum; V. R. Koch; L. L. Miller; R. A. Osteryoung. Electrochemical scrutiny of organometallic iron complexes and hexamethylbenzene in a room temperature molten salt. J. Am. Chem. Soc.1975, 97 (11), 3264-3265.
  2. Oxidative rearrangement occurs on treatment with peroxytrifluoroacetic acid (caution! 90% H2O2) and BF3 etherate to give hexamethyl-2,4-cyclohexadienone: J. Am. Chem. Soc., 88, 1005 (1966); Org. Synth. Coll., 5, 598 (1973). Reaction with dimethyldioxirane, on the other hand, gives, as the major product, an unusual oxepane triepoxide: J. Org. Chem., 61, 7660 (1996):