3-Phenylpropionaldehyde, 95%, Thermo Scientific Chemicals
3-Phenylpropionaldehyde, 95%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

3-Phenylpropionaldehyde, 95%, Thermo Scientific Chemicals

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Catalog number A10367.18
also known as A10367-18
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Quantity:
50 g
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Price (USD)/ Each
44.65
Online exclusive
49.20 
Save 4.55 (9%)
Add to cart
3-Phenylpropionaldehyde, 95%, Thermo Scientific Chemicals
Catalog numberA10367.18
Price (USD)/ Each
44.65
Online exclusive
49.20 
Save 4.55 (9%)
-
Add to cart
Chemical Identifiers
CAS104-53-0
IUPAC Name3-phenylpropanal
Molecular FormulaC9H10O
InChI KeyYGCZTXZTJXYWCO-UHFFFAOYSA-N
SMILESO=CCCC1=CC=CC=C1
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SpecificationsSpecification SheetSpecification Sheet
Refractive Index1.5210-1.5300 @ 20?C
Appearance (Color)Clear colorless to pale yellow
FormLiquid
Assay (GC)≥94.0%
Free acid (titration)≤2.0%
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3-Phenylpropionaldehyde is used as a flavoring agent. It is also used in the preparation of cinnamaldehyde, 2-chloro hydrocinnamaldehyde by alfa chlorination and mixture of homopropargyl alcohols. It serves as a precursor for the synthesis of mixture of syn- and anti-beta-hydroxyallylsilanes by hydroboration of allenylsilane. It is also involved in the catalytic asymmetric cyanosilylation to prepare (2S)-2-hydroxy-4-phenylbutanenitrile. Further, it undergoes Henry reaction to form nitroaldols by reacting with nitromethane.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Phenylpropionaldehyde is used as a flavoring agent. It is also used in the preparation of cinnamaldehyde, 2-chloro hydrocinnamaldehyde by alfa chlorination and mixture of homopropargyl alcohols. It serves as a precursor for the synthesis of mixture of syn- and anti-beta-hydroxyallylsilanes by hydroboration of allenylsilane. It is also involved in the catalytic asymmetric cyanosilylation to prepare (2S)-2-hydroxy-4-phenylbutanenitrile. Further, it undergoes Henry reaction to form nitroaldols by reacting with nitromethane.

Solubility
Miscible with chloroform, dichloromethane, ethyl acetate, alcohol and ether. Immiscible with water.

Notes
Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only

General References:

  1. Durndell, L. J.; Wilson, K.; Lee, A. F. Platinum-catalysed cinnamaldehyde hydrogenation in continuous flow. RSC Adv. 2015, 5 (97), 80022-80026.
  2. Kashyap, B.; Phukan, P. CuI catalyzed Barbier type allylation of aldehyde in presence of S1,S2-dipyridin-2-yl ferrocene-1,1'-dicarbothioate as ligand. Indian J. Chem. 2015, 54, 662-670.