Thermo Scientific Chemicals

(+)-Diethyl L-tartrate, 98%, Thermo Scientific Chemicals

Catalog number: A10641.0B
1000 g, Each
Thermo Scientific Chemicals

(+)-Diethyl L-tartrate, 98%, Thermo Scientific Chemicals

Catalog number: A10641.0B
1000 g, Each
Quantity
Catalog number: A10641.0B
also known as A10641-0B
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Chemical Identifiers

CAS
87-91-2
IUPAC Name
1,4-diethyl 2,3-dihydroxybutanedioate
Molecular Formula
C8H14O6
InChI Key
YSAVZVORKRDODB-UHFFFAOYNA-N
SMILES
CCOC(=O)C(O)C(O)C(=O)OCC
Appearance (Color)
Clear colorless
Form
Liquid
Identification (FTIR)
Conforms
Refractive Index
1.4445-1.4485 @ 20?C
Assay (GC)
≥98.5%

Description

(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

Solubility
Fully miscible in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
RUO – Research Use Only

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