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Diethyl bromomalonate, 90+%, Thermo Scientific Chemicals
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Catalog number A10965.14
also known as A10965-14
Price (USD)/ Each
38.80
-
Quantity:
25 g
Price (USD)/ Each
38.80
Diethyl bromomalonate, 90+%, Thermo Scientific Chemicals
Catalog numberA10965.14
Price (USD)/ Each
38.80
-
Chemical Identifiers
CAS685-87-0
IUPAC Name1,3-diethyl 2-bromopropanedioate
Molecular FormulaC7H11BrO4
InChI KeyFNJVDWXUKLTFFL-UHFFFAOYSA-N
SMILESCCOC(=O)C(Br)C(=O)OCC
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Specifications
Specification Sheet
Specification SheetAssay (unspecified)≥90.0%
Diethyl bromomalonate is used in perfumes. It is also used to synthesize other compounds such as barbiturates, artificial flavorings, vitamin B1, and vitamin B6.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Diethyl bromomalonate is used in perfumes. It is also used to synthesize other compounds such as barbiturates, artificial flavorings, vitamin B1, and vitamin B6.
Solubility
Does not mix well with water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store at room temperature. Incompatible with strong oxidizing agents and strong bases.
Diethyl bromomalonate is used in perfumes. It is also used to synthesize other compounds such as barbiturates, artificial flavorings, vitamin B1, and vitamin B6.
Solubility
Does not mix well with water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store at room temperature. Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only
General References:
- Gregory Socrates Coumbarides.; Marco Dingjan.; Jason Eames.; Neluka Weerasooriya. Investigations into the Bromination of Substituted Phenols using Diethyl Bromomalonate and Diethyl Dibromomalonate. Bulletin of the Chemical Society of Japan. 2001, 74, (1), 179-180.
- Ru-Fang Peng.; Guan-Wu Wang.; Ye-Bing Shen.; Yu-Jin Li.; Ting-Hu Zhang.; You-Cheng Liu.;Yasujiro Murata.; Koichi Komatsu. Solvent-Free Reactions of Fullerenes with Diethyl Bromomalonate in the Presence of Inorganic Bases Under High-Speed Vibration Milling Conditions. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 2004, 34, (11), 2117-2126.
- In the presence of 1,8-Diazabicyclo[5.4.0]undec-7-ene, A12449, and CuBr2, reacts with styrenes or alkenes with electron-withdrawing groups to give 2-substituted cyclopropane-1,1-dicarboxylate esters: Bull. Chem. Soc. Jpn., 55, 2687 (1982).
- Condenses with substituted o-hydroxyacetophenones in a convenient synthesis of 2-aryl-3(2H)-benzofuranones: Synth. Commun., 23, 961 (1993):