4-Bromo-1-butene, 97%, Thermo Scientific Chemicals
4-Bromo-1-butene, 97%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

4-Bromo-1-butene, 97%, Thermo Scientific Chemicals

Have Questions?
Change viewbuttonViewtableView
Quantity:
25 g
5 g
Catalog number A10977.14
also known as A10977-14
Price (USD)/ Each
235.65
Online exclusive
262.00 
Save 26.35 (10%)
-
Add to cart
Quantity:
25 g
Request bulk or custom format
Price (USD)/ Each
235.65
Online exclusive
262.00 
Save 26.35 (10%)
Add to cart
4-Bromo-1-butene, 97%, Thermo Scientific Chemicals
Catalog numberA10977.14
Price (USD)/ Each
235.65
Online exclusive
262.00 
Save 26.35 (10%)
-
Add to cart
Chemical Identifiers
CAS5162-44-7
IUPAC Name4-bromobut-1-ene
Molecular FormulaC4H7Br
InChI KeyDMAYBPBPEUFIHJ-UHFFFAOYSA-N
SMILESBrCCC=C
View more
SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Clear colorless to yellow
Assay (GC)≥96.0%
Refractive Index1.4600-1.4655 @ 20?C
Identification (FTIR)Conforms
FormLiquid
4-Bromo-1-butene is used in the preparation of 4-(3-butenyloxy)benzoic acid and largazole. It is also used in double alkylation of lactams followed by Grubbs ring-closing metathesis to yield gymnodimine. Further, it serves as a reagent in the preparation of dienehydrazides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Bromo-1-butene is used in the preparation of 4-(3-butenyloxy)benzoic acid and largazole. It is also used in double alkylation of lactams followed by Grubbs ring-closing metathesis to yield gymnodimine. Further, it serves as a reagent in the preparation of dienehydrazides.

Solubility
Miscible with water, benzene, ether and ethanol.

Notes
Light sensitive. Store in a cool place. Incompatible with strong bases.
RUO – Research Use Only

General References:

  1. Hoyt, J. M.; Schmidt, V. A.; Tondreau, A. M.; Chirik, P. J. Iron-catalyzed intermolecular [2+2] cycloadditions of unactivated alkenes. Science 2015, 349 (6251), 960-963.
  2. Liu, T.; Nie, Y.; Chen, R.; Zhang, L.; Meng, Y.; Li, X. Hyperbranched polyether as an all-purpose epoxy modifier: controlled synthesis and toughening mechanisms. J. Mater. Chem. A 2015, 3 (3), 1188-1198.