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Ethyl 4-bromobenzoate, 98+%, Thermo Scientific Chemicals
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Catalog number A11365.18
also known as A11365-18
Price (USD)/ Each
88.50
-
Quantity:
50 g
Price (USD)/ Each
88.50
Ethyl 4-bromobenzoate, 98+%, Thermo Scientific Chemicals
Catalog numberA11365.18
Price (USD)/ Each
88.50
-
Chemical Identifiers
CAS5798-75-4
IUPAC Nameethyl 4-bromobenzoate
Molecular FormulaC9H9BrO2
InChI KeyXZIAFENWXIQIKR-UHFFFAOYSA-N
SMILESCCOC(=O)C1=CC=C(Br)C=C1
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Specifications
Specification Sheet
Specification SheetFormLiquid
Refractive Index1.5440-1.5480 @ 20?C
Appearance (Color)Clear colorless to yellow
Assay (GC)≥98.0%
Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.
Solubility
Slightly soluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.
Solubility
Slightly soluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only
General References:
- Chae MJ, et al. Chemoselective Reduction of Esters to Aldehydes by Potassium Diisobutyl-t-butoxyaluminum Hydride (PDBBA). Bull. Korean Chem. Soc. 2007, 28 (12), 2517.
- John M. Herbert. Negishi-type coupling of bromoarenes with dimethylzinc. Tetrahedron Letters. 2004, 45 (4), 817-819.