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Ethyl 2-methylacetoacetate, 95%, Thermo Scientific Chemicals
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Catalog number A11629.14
also known as A11629-14
Price (USD)/ Each
48.80
-
Quantity:
25 g
Price (USD)/ Each
48.80
Ethyl 2-methylacetoacetate, 95%, Thermo Scientific Chemicals
Catalog numberA11629.14
Price (USD)/ Each
48.80
-
Chemical Identifiers
CAS609-14-3
IUPAC Nameethyl 2-methyl-3-oxobutanoate
Molecular FormulaC7H12O3
InChI KeyFNENWZWNOPCZGK-UHFFFAOYNA-N
SMILESCCOC(=O)C(C)C(C)=O
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Specifications
Specification Sheet
Specification SheetFormLiquid
Refractive Index1.4155-1.4215 @ 20?C
Appearance (Color)Clear colorless to yellow
Assay (GC)≥94.0%
Ethyl 2-methylacetoacetate is used in Japp-Klingemann reaction to prepare hydrazones from beta-keto acid and aryl diazonium salts. It is used as a precursor involved in the synthesis of ethylpyruvate phenylhydrazone via reaction with benzenediazonium chloride.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Ethyl 2-methylacetoacetate is used in Japp-Klingemann reaction to prepare hydrazones from beta-keto acid and aryl diazonium salts. It is used as a precursor involved in the synthesis of ethylpyruvate phenylhydrazone via reaction with benzenediazonium chloride.
Solubility
Miscible with alcohol and ether. Silghtly miscible with water.
Notes
Incompatible with strong oxidizing agents and strong bases.
Ethyl 2-methylacetoacetate is used in Japp-Klingemann reaction to prepare hydrazones from beta-keto acid and aryl diazonium salts. It is used as a precursor involved in the synthesis of ethylpyruvate phenylhydrazone via reaction with benzenediazonium chloride.
Solubility
Miscible with alcohol and ether. Silghtly miscible with water.
Notes
Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only
General References:
- Kula, S.; Szlapa, A.; Malecki, J. G.; Maron, A.; Matussek, M.; Balcerzak, E. S.; Siwy, M.; Domanski, M.; Sojka, M.; Danikiewicz, W.; Krompiec, S.; Filapek, M. Synthesis and photophysical properties of novel multisubstituted benzene and naphthalene derivatives with high 2D-pi-conjugation. Opt. Mater. 2015, 47, 118-128.
- Hatamur, M.; Yamaguchi, S.; Takane, S.; Chen, Y.; Suganuma, K. Decarboxylation and simultaneous reduction of silver(I) beta-ketocarboxylates with three. Dalton Trans. 2015, 44 (19), 8993-9003.