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Allyl trifluoroacetate, 97%, Thermo Scientific Chemicals
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Catalog number A11690.09
also known as A11690-09
Price (USD)/ Each
40.40
-
Quantity:
10 g
Price (USD)/ Each
40.40
Allyl trifluoroacetate, 97%, Thermo Scientific Chemicals
Catalog numberA11690.09
Price (USD)/ Each
40.40
-
Chemical Identifiers
CAS383-67-5
IUPAC Nameprop-2-en-1-yl 2,2,2-trifluoroacetate
Molecular FormulaC5H5F3O2
InChI KeyXIVPVSIDXBTZLM-UHFFFAOYSA-N
SMILESFC(F)(F)C(=O)OCC=C
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Specifications
Specification Sheet
Specification SheetFormLiquid
Appearance (Color)Clear colorless to yellow to pale brown
Identification (FTIR)Conforms
Refractive Index1.3340-1.3390 @ 20°C
Assay (GC)≥96.0%
Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.
Solubility
Not miscible or difficult to mix with water.
Notes
Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.
Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.
Solubility
Not miscible or difficult to mix with water.
Notes
Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.
RUO – Research Use Only
General References:
- Robin E. Grote; and Elizabeth R. Jarvo. Palladium-Catalyzed, One-Pot, Three-Component Synthesis of Homoallylic Amines from Aldehydes, Anisidine, and Allyl Trifluoroacetate. Org. Lett. 2009, 11 (2), 485-488.
- Debby de Groot; Janine C. de Wilde; Richard J. van Haaren; Joost N. H. Reek; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Eva B. Eggeling; Dieter Vogt; Huub Kooijman; Anthony L. Spek and Alexander W. van der Made . Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor. Chem. Commun. 1999, (17), 1623-1624.