Thermo Scientific Chemicals

Pyridinium chlorochromate, 98%, Thermo Scientific Chemicals

Catalog number: A11752.36
500 g, Each
Thermo Scientific Chemicals

Pyridinium chlorochromate, 98%, Thermo Scientific Chemicals

Catalog number: A11752.36
500 g, Each
Quantity
Catalog number: A11752.36
also known as A11752-36
Price (USD)
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Chemical Identifiers

CAS
26299-14-9
IUPAC Name
hydrogen (trioxochromio)-λ³-chloranidyl pyridine
Molecular Formula
C5H6ClCrNO3
InChI Key
BUCMHZVAGRYTNK-UHFFFAOYSA-O
SMILES
[H+].[Cl-][Cr](=O)(=O)=O.C1=CC=NC=C1
Assay (Iodometric Titration)
≥97.5 to ≤102.5%
Form
Crystals or powder or crystalline powder
Identification (FTIR)
Conforms
Appearance (Color)
Orange

Description

Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.

Solubility
Soluble in acetone, benzene, dichloromethane, acetonitrile and tetrahydrofuran.

Notes
Incompatible with alcohols, acetone and methanol.
WARNING: Cancer and Reproductive Harm – www.P65Warnings.ca.gov
RUO – Research Use Only

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