o-Phenylenediamine, 98%, Thermo Scientific Chemicals
o-Phenylenediamine, 98%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

o-Phenylenediamine, 98%, Thermo Scientific Chemicals

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Catalog number A11946.0I
also known as A11946-0I
Price (USD)/ Each
499.65
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555.00 
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Quantity:
5000 g
Request bulk or custom format
Price (USD)/ Each
499.65
Online exclusive
555.00 
Save 55.35 (10%)
Add to cart
o-Phenylenediamine, 98%, Thermo Scientific Chemicals
Catalog numberA11946.0I
Price (USD)/ Each
499.65
Online exclusive
555.00 
Save 55.35 (10%)
-
Add to cart
Chemical Identifiers
CAS95-54-5
IUPAC Namebenzene-1,2-diamine
Molecular FormulaC6H8N2
InChI KeyGEYOCULIXLDCMW-UHFFFAOYSA-N
SMILESNC1=CC=CC=C1N
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to pale brown
Assay (GC)≥97.5%
Melting Point (clear melt)99-104?C
FormCrystals, flakes or pellets
Identification (FTIR)Conforms
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o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.

Solubility
Soluble in alcohol, chloroform, ether, slightly soluble in water. Soluble in hot water.

Notes
Moisture and air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
WARNING: Cancer – www.P65Warnings.ca.gov
RUO – Research Use Only

General References:

  1. Chen, X.; Zhang, Q.; Qian, C.; Hao, N.; Xu, L.; Yao, C. Electrochemical aptasensor for mucin 1 based on dual signal amplification of poly (o-phenylenediamine) carrier and functionalized carbon nanotubes tracing tag. Biosens. Bioelectron. 2015, 64, 485-492.
  2. Yuan, C.; Liu, X.; Jia, M.; Luo, Z.; Yao, J. Facile preparation of N-and O-doped hollow carbon spheres derived from poly (o-phenylenediamine) for supercapacitors. J. Mater. Chem. A 2015, 3 (7), 3409-3415.