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Benzophenone hydrazone, 98+%, Thermo Scientific Chemicals
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Catalog number A12266.30
also known as A12266-30
Price (USD)/ Each
80.00
-
Quantity:
250 g
Price (USD)/ Each
80.00
Benzophenone hydrazone, 98+%, Thermo Scientific Chemicals
Catalog numberA12266.30
Price (USD)/ Each
80.00
-
Chemical Identifiers
CAS5350-57-2
IUPAC Name(diphenylmethylidene)hydrazine
Molecular FormulaC13H12N2
InChI KeyQYCSNMDOZNUZIT-UHFFFAOYSA-N
SMILESNN=C(C1=CC=CC=C1)C1=CC=CC=C1
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Specifications
Specification Sheet
Specification SheetFormcrystals or crystalline powder
Appearance (Color)White to yellow or pale brown
Assay (GC)>98.0%
An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.
Solubility
Soluble in ether, benzene, chloroform and other organic solvents.
Notes
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4 C/39 F.)
An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.
Solubility
Soluble in ether, benzene, chloroform and other organic solvents.
Notes
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4 C/39 F.)
RUO – Research Use Only
General References:
- G. Anandha Babua,; R. Perumal Ramasamy,; P. Ramasamya,; S. Natarajanb. Studies on the crystal growth, crystal structure, optical and thermal properties of an organic crystal: Benzophenone hydrazone . Journal of Crystal Growth. 2009, 311(13), 3461-3465.
- H. Harry Szmant,; Mirta N. Román. The Effect of Dimethyl Sulfoxide on the Rate of the Wolff-Kishner Reaction of Benzophenone Hydrazone . J. Am. Chem. Soc. 1966 , 88 (17),4034-4039.
- Oxidation with e.g. HgO: Org. Synth. Coll., 3, 351 (1955), peracetic acid and tetramethylguanidine: J. Chem. Soc., Perkin 1, 2030 (1975), iodosobenzene diacetate: Synthesis, 513 (1985) or potassium monopersulfate: Tetrahedron Lett., 38, 1239 (1997), gives diphenyldiazomethane, a reagent for the protection of carboxylic acids by conversion to their benzhydryl esters. The protecting group can be cleaved by hydrogenolysis: Helv. Chim. Acta, 31, 439 (1938), or mild acid: J. Am. Chem. Soc., 87, 3969, 5469 (1965). See Appendix 6.