Thermo Scientific Chemicals

(Trimethylsilyl)acetylene, 98%, Thermo Scientific Chemicals

Catalog number: A12856.14
25 g, Each
Thermo Scientific Chemicals

(Trimethylsilyl)acetylene, 98%, Thermo Scientific Chemicals

Catalog number: A12856.14
25 g, Each
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Catalog number: A12856.14
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Chemical Identifiers

CAS
1066-54-2
IUPAC Name
ethynyltrimethylsilane
Molecular Formula
C5H10Si
InChI Key
CWMFRHBXRUITQE-UHFFFAOYSA-N
SMILES
C[Si](C)(C)C#C
Assay (GC)
≥97.5%
Refractive Index
1.3875-1.3920 @ 20?C
Appearance (Color)
Clear colorless
Form
Liquid
Identification (FTIR)
Conforms

Description

(Trimethylsilyl)acetylene is used in the preparation of trimethylsilanyl-propiolic acid ethyl ester by reacting with carbonochloridic acid ethyl ester as well as in the synthesis of iodoalkenes by radical addition of perfluoroalkyl iodides. It is used as a nucleophile in Friedel-Crafts type acylations and alkylations reactions, as a ligand in organometallic chemistry and an useful reagent in cycloaddition reactions. It acts as a precursor to lithium trimethylsilylacetylide It finds application in the synthesis of (±)-estrone.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Trimethylsilyl)acetylene is used in the preparation of trimethylsilanyl-propiolic acid ethyl ester by reacting with carbonochloridic acid ethyl ester as well as in the synthesis of iodoalkenes by radical addition of perfluoroalkyl iodides. It is used as a nucleophile in Friedel-Crafts type acylations and alkylations reactions, as a ligand in organometallic chemistry and an useful reagent in cycloaddition reactions. It acts as a precursor to lithium trimethylsilylacetylide It finds application in the synthesis of (±)-estrone.

Solubility
Miscible with organic solvents.

Notes
Store in a cool place. Incompatible with strong oxidizing agents.
RUO – Research Use Only

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