(1-Propyl)triphenylphosphonium bromide, 99%, Thermo Scientific Chemicals
(1-Propyl)triphenylphosphonium bromide, 99%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

(1-Propyl)triphenylphosphonium bromide, 99%, Thermo Scientific Chemicals

Have Questions?
Change viewbuttonViewtableView
Quantity:
50 g
250 g
1000 g
Catalog number A12968.18
also known as A12968-18
Price (USD)/ Each
48.80
-
Add to cart
Quantity:
50 g
Request bulk or custom format
Price (USD)/ Each
48.80
Add to cart
(1-Propyl)triphenylphosphonium bromide, 99%, Thermo Scientific Chemicals
Catalog numberA12968.18
Price (USD)/ Each
48.80
-
Add to cart
Chemical Identifiers
CAS6228-47-3
IUPAC Nametriphenyl(propyl)phosphanium bromide
Molecular FormulaC21H22BrP
InChI KeyXMQSELBBYSAURN-UHFFFAOYSA-M
SMILES[Br-].CCC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
View more
SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White
FormCrystals or powder or crystalline powder
Assay (Titration ex Bromide)≥98.5 to ≤101.5%
Identification (FTIR)Conforms
Melting Point (clear melt)232-238?C
It is employed as a catalyst for the carboxylation of styrene oxide and as a reactant involved in epoxidation of arylalkenes, boration of allylic epoxides, Wittig reactions, selective dimerization of α-olefins, and synthesis of indoles. It has also been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is employed as a catalyst for the carboxylation of styrene oxide and as a reactant involved in epoxidation of arylalkenes, boration of allylic epoxides, Wittig reactions, selective dimerization of α-olefins, and synthesis of indoles. It has also been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A.

Solubility
Soluble in water.

Notes
Hygroscopic. Store away from oxidizing agents, humidity and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
RUO – Research Use Only

General References:

  1. Mariola Tortosa. Synthesis of syn and anti 1,4-diols by copper-catalyzed boration of allylic epoxides.Angew Chem Int Ed Engl.,2011,50(17),3950-3953.
  2. Hisato Nonaka, et. al. Stereoselective synthesis of epi-jasmonic acid, tuberonic acid, and 12-oxo-PDA.Org Biomol Chem.,2010,22(8), 5212-5223.