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2-Aminobenzyl alcohol, 98%, Thermo Scientific Chemicals
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Catalog number A13180.18
also known as A13180-18
Price (USD)/ Each
110.00
-
Quantity:
50 g
Price (USD)/ Each
110.00
2-Aminobenzyl alcohol, 98%, Thermo Scientific Chemicals
Catalog numberA13180.18
Price (USD)/ Each
110.00
-
Chemical Identifiers
CAS5344-90-1
IUPAC Name(2-aminophenyl)methanol
Molecular FormulaC7H9NO
InChI KeyVYFOAVADNIHPTR-UHFFFAOYSA-N
SMILESNC1=CC=CC=C1CO
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Specifications
Specification Sheet
Specification SheetIdentification (FTIR)Conforms
Melting Point81.0-86.0°C
FormCrystals or powder or crystalline powder
Appearance (Color)White to cream to yellow to brown
Assay (GC)≥97.5%
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
Solubility
Very soluble in water.
Notes
Store at room temperature. Incompatible with oxidizing agents.
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
Solubility
Very soluble in water.
Notes
Store at room temperature. Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- Chan Sik Cho.; Bok Tae Kim.; Tae-Jeong Kim.; Sang Chul Shim. Ruthenium-catalysed oxidative cyclisation of 2-aminobenzyl alcohol with ketones: modified Friedlaender quinoline synthesis.Chem. Commun. 2001, (24),2576-2577 .
- Chan Sik Cho.; Bok Tae Kim.; Heung-Jin Choi.; Tae-Jeong Kim.; Sang Chul Shim. Ruthenium-catalyzed oxidative coupling and cyclization between 2-aminobenzyl alcohol and secondary alcohols leading to quinolines. Tetrahedron. 2003, 59 (40),7997-8002 .