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Chlorotriphenylsilane, 96%, Thermo Scientific Chemicals
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Catalog number A13678.14
also known as A13678-14
Price (USD)/ Each
75.65
Online exclusive
83.80 Save 8.15 (10%)
-
Quantity:
25 g
Price (USD)/ Each
75.65
Online exclusive
83.80 Save 8.15 (10%)
Chlorotriphenylsilane, 96%, Thermo Scientific Chemicals
Catalog numberA13678.14
Price (USD)/ Each
75.65
Online exclusive
83.80 Save 8.15 (10%)
-
Chemical Identifiers
CAS76-86-8
IUPAC Namechlorotriphenylsilane
Molecular FormulaC18H15ClSi
InChI KeyMNKYQPOFRKPUAE-UHFFFAOYSA-N
SMILESCl[Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
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Specifications
Specification Sheet
Specification SheetFormCrystals or powder or crystalline powder or lumps or chunks or fused solid
Identification (FTIR)Conforms
Assay (GC)≥95.0%
Melting Point (clear melt)87.0-99.0?C
Appearance (Color)Colorless to white
Chlorotriphenylsilane is used as a silylating agent. It is also used as a pharmaceutical intermediate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Chlorotriphenylsilane is used as a silylating agent. It is also used as a pharmaceutical intermediate.
Solubility
Reacts with water.
Notes
Keep container tightly sealed. Store under dry inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.
Chlorotriphenylsilane is used as a silylating agent. It is also used as a pharmaceutical intermediate.
Solubility
Reacts with water.
Notes
Keep container tightly sealed. Store under dry inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.
RUO – Research Use Only
General References:
- Raymond C. Petersen.; Sidney D. Ross. Displacement Reactions on Silicon. The Reaction of 2-Propanol with Chlorotriphenylsilane in Carbon Tetrachloride. J. Am. Chem. Soc. 1963, 85 (20), 3164-3167.
- Henry Gilman.; Glen D. Lichtenwalter. Cleavage of Symmetrically Substituted Disilanes by Lithium in Tetrahydrofuran. J. Am. Chem. Soc. 1958, 80 (3), 608-611.
- Silylating agent: J. Chem. Soc., 3403 (1963); see Appendix 4. The stability of the bulky triphenylsilyl (TPS) ethers to basic hydrolysis is similar to TMS, but they are about 400x more stable to acid hydrolysis. Suitable conditions for their cleavage include: ethanolic NaOH; AcOH - water - THF at 70°: Chem. Lett., 1499 (1979); and TBAF: J. Am .Chem. Soc., 108, 3827 (1986).