2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.
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Applications
2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.
Solubility
Miscible with water.
Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.
RUO – Research Use Only
Lu, X.; Wang, H.; Gao, R.; Pei, C. One-pot Metal-free Synthesis of Benzyl Alkyl Sulfides. Phosphorus Sulfur Silicon Relat Elem 2015, 190 (1), 45-52.
Huang, R.; Huang, Y.; Lin, X.; Rong, M.; Weng, Z. Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides. Angew. Chem. Int. Ed. 2015, 54 (19), 5736-5739.