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Triphenylphosphine, flake, 99%, Thermo Scientific Chemicals
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Catalog number A14089.30
also known as A14089-30
Price (USD)/ Each
51.65
Online exclusive
57.40 Save 5.75 (10%)
-
Quantity:
250 g
Price (USD)/ Each
51.65
Online exclusive
57.40 Save 5.75 (10%)
Triphenylphosphine, flake, 99%, Thermo Scientific Chemicals
Catalog numberA14089.30
Price (USD)/ Each
51.65
Online exclusive
57.40 Save 5.75 (10%)
-
Chemical Identifiers
CAS603-35-0
IUPAC Nametriphenylphosphane
Molecular FormulaC18H15P
InChI KeyRIOQSEWOXXDEQQ-UHFFFAOYSA-N
SMILESC1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1
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Specifications
Specification Sheet
Specification SheetIdentification (FTIR)Conforms
Melting Point (clear melt)78.0-85.0?C
Appearance (Color)White
FormFlakes
Assay (GC)≥98.5%
In the synthesis of organic compounds, phosphonium salts and other phosphorus compounds, and as a polymerization initiatorTriphenylphosphine is used in the synthesis of organic compounds due to its nucleophilicity and its reducing character. It is involved in the synthesis of biaryl compounds, phosphonium salts and other phosphorus compounds. As a reducing agent, it is used to prepare aromatic amines from the corresponding aromatic N-oxides. The anionic phosphine is usually isolated as the trisodium salt, which reacts with rhodium to form a complex that finds use in industrial hydroformylation reactions. It is also used to prepare Wilkinson's catalyst, RhCl(PPh3)3 useful to catalyze the hydrogenation of alkenes and tetrakis(triphenylphosphine)palladium(0) that is widely used to catalyse C-C coupling reactions in organic synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
In the synthesis of organic compounds, phosphonium salts and other phosphorus compounds, and as a polymerization initiatorTriphenylphosphine is used in the synthesis of organic compounds due to its nucleophilicity and its reducing character. It is involved in the synthesis of biaryl compounds, phosphonium salts and other phosphorus compounds. As a reducing agent, it is used to prepare aromatic amines from the corresponding aromatic N-oxides. The anionic phosphine is usually isolated as the trisodium salt, which reacts with rhodium to form a complex that finds use in industrial hydroformylation reactions. It is also used to prepare Wilkinson′s catalyst, RhCl(PPh3)3 useful to catalyze the hydrogenation of alkenes and tetrakis(triphenylphosphine)palladium(0) that is widely used to catalyse C-C coupling reactions in organic synthesis.
Notes
Incompatible with oxidizing agents and acids.
In the synthesis of organic compounds, phosphonium salts and other phosphorus compounds, and as a polymerization initiatorTriphenylphosphine is used in the synthesis of organic compounds due to its nucleophilicity and its reducing character. It is involved in the synthesis of biaryl compounds, phosphonium salts and other phosphorus compounds. As a reducing agent, it is used to prepare aromatic amines from the corresponding aromatic N-oxides. The anionic phosphine is usually isolated as the trisodium salt, which reacts with rhodium to form a complex that finds use in industrial hydroformylation reactions. It is also used to prepare Wilkinson′s catalyst, RhCl(PPh3)3 useful to catalyze the hydrogenation of alkenes and tetrakis(triphenylphosphine)palladium(0) that is widely used to catalyse C-C coupling reactions in organic synthesis.
Notes
Incompatible with oxidizing agents and acids.
RUO – Research Use Only
General References:
- Lenstra, D. C.; Rutjes, F. P.; Mecinovic, J. Triphenylphosphine-catalysed amide bond formation between carboxylic acids and amines. Chem. Commun. 2014, 50 (43), 5763-5766.
- Maleki, A.; Rahimi, R.; Maleki, S.; Hamidi, N. Synthesis and characterization of magnetic bromochromate hybrid nanomaterials with triphenylphosphine surface-modified iron oxide nanoparticles and their catalytic application in multicomponent reactions. RSC Adv. 2014, 4 (56), 29765-29771.