2,6-Difluoropyridine has been used in the preparation of poly(pyridine ether)s via polycondensation with silylated 1,1,1-tris(4-hydroxyphenyl)ethane.
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Applications
2,6-Difluoropyridine has been used in the preparation of poly(pyridine ether)s via polycondensation with silylated 1,1,1-tris(4-hydroxyphenyl)ethane.
Solubility
Not miscible or difficult to mix.
Notes
Store in a cool, dry conditions in a well sealed container. Incompatible with oxidizing agent.
RUO – Research Use Only
General References:
- Lekha Gupta; Alexander C Hoepker; Yun Ma; Mihai S Viciu; Marc F Faggin; David B Collum. Lithium diisopropylamide-mediated ortholithiation of 2-fluoropyridines: rates, mechanisms, and the role of autocatalysis. Journal of Organic Chemistry. 2013, 78 (9), 4214-4230.
- Hans R. Kricheldorf; Gert Schwarz andJörg Erxleben. New polymer syntheses, 27. Syntheses of aromatic polyethers from 2,6-difluoropyridine and silylated aromatic diols. Macromol. Chem. Phys. 1988, 189, (10), 2255-2267.
- Sequential displacement of the fluorine atoms with nitrogen has been used in the synthesis of linear and macrocyclic ligands: J. Chem. Soc., Perkin 1, 423 (1998).