Calcium hydride, coarse powder, ca 92%, Thermo Scientific Chemicals
Calcium hydride, coarse powder, ca 92%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Calcium hydride, coarse powder, ca 92%, Thermo Scientific Chemicals

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250 g
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1000 g
Catalog number A16242.30
also known as A16242-30
Price (USD)/ Each
201.65
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224.00 
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Quantity:
250 g
Request bulk or custom format
Price (USD)/ Each
201.65
Online exclusive
224.00 
Save 22.35 (10%)
Add to cart
Calcium hydride, coarse powder, ca 92%, Thermo Scientific Chemicals
Catalog numberA16242.30
Price (USD)/ Each
201.65
Online exclusive
224.00 
Save 22.35 (10%)
-
Add to cart
Chemical Identifiers
CAS7789-78-8
IUPAC Namecalcium
Molecular FormulaCa
InChI KeyOYPRJOBELJOOCE-UHFFFAOYSA-N
SMILES[Ca]
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Pale grey to grey
FormPowder and granules
Elemental AnalysisCa ≥92%
Particle Size1 to 20 mm (approx.)
Calcium hydride is used as an efficient drying agent for aprotic base-stable solvents like ethers and tertiary amines. It is a useful dehydrating agent in a synthesis of aldehyde enamines in high yield and purity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Calcium chloride is used as an efficient drying agent for aprotic base-stable solvents like ethers and tertiary amines. It is a useful dehydrating agent in a synthesis of aldehyde enamines in high yield and purity.

Solubility
Soluble in water and alcohol. Insoluble in benzene.

Notes
Moisture sensitive. Reacts with water vigorously and liberates hydrogen gas. Incompatible with strong oxidizing agents, strong acids, halogens, water and alcohols.
RUO – Research Use Only

General References:

  1. Efficient drying agent for aprotic, base-stable solvents, particularly useful for ethers and tertiary amines.
  2. Has been used as a dehydrating agent in a synthesis of aldehyde enamines in high yield and purity: Synth. Commun., 24, 1541 (1994).
  3. Liu, Y.; Wang, X.; Liu, H.; Dong, Z.; Li, S.; Ge, H.; Yan, M. Investigation on the improved hydrolysis of aluminum-calcium hydride-salt mixture elaborated by ball milling. Energy 2015, 84, 714-721.
  4. Leich, V.; Spaniol, T. P.; Okuda, J. Formation of a Cationic Calcium Hydride Cluster with a Naked Triphenylsilyl Anion by Hydrogenolysis of Bis(triphenylsilyl)calcium. Inorg. Chem. 2015, 54 (10), 4927-4933.