Thermo Scientific Chemicals

Triphenylphosphine sulfide, 98%, Thermo Scientific Chemicals

Catalog number: A16884.22
100 g, Each
Thermo Scientific Chemicals

Triphenylphosphine sulfide, 98%, Thermo Scientific Chemicals

Catalog number: A16884.22
100 g, Each
Quantity
Catalog number: A16884.22
also known as A16884-22
Price (USD)
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Chemical Identifiers

CAS
3878-45-3
IUPAC Name
triphenyl-λ⁵-phosphanethione
Molecular Formula
C18H15PS
InChI Key
VYNGFCUGSYEOOZ-UHFFFAOYSA-N
SMILES
S=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Assay (GC)
>97.5%
Appearance (Color)
White
Form
Crystals or crystalline powder

Description

Triphenylphosphine sulfide involves in the , conversion of epoxides to episulfides (thiiranes) in presence of TFA of the same stereochemistry. It acts as a ligand for the Pd-catalyzed bisalkoxycarbonylation of olefins.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triphenylphosphine sulfide involves in the , conversion of epoxides to episulfides (thiiranes) in presence of TFA of the same stereochemistry. It acts as a ligand for the Pd-catalyzed bisalkoxycarbonylation of olefins.

Solubility
Insoluble in water.

Notes
Store in a cool, dry, conditions in well sealed container. Store away from oxidizing agents.
RUO – Research Use Only

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