Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.
Solubility
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.
Notes
Light sensitive and hygroscopic. Incompatible with strong acids.
RUO – Research Use Only
General References:
- Cahard, E.; Male, H. P. J.; Tissot, M.; Gaunt, M. J. Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts. J. Am. Chem. Soc. 2015, 137 (25), 7986-7989.
- He, C.; Stoykovich, M. P. Photopatterning of Cross-Linkable Epoxide-Functionalized Block Copolymers and Dual-Tone Nanostructure Development for Fabrication Across the Nano-and Microscales. Small 2015, 11 (20), 2407-2416.