Diphenyliodonium hexafluorophosphate, 98%, Thermo Scientific Chemicals
Diphenyliodonium hexafluorophosphate, 98%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Diphenyliodonium hexafluorophosphate, 98%, Thermo Scientific Chemicals

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Catalog number A17934.09
Price (USD)/ Each
99.65
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111.00 
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Quantity:
10 g
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Price (USD)/ Each
99.65
Online exclusive
111.00 
Save 11.35 (10%)
Add to cart
Diphenyliodonium hexafluorophosphate, 98%, Thermo Scientific Chemicals
Catalog numberA17934.09
Price (USD)/ Each
99.65
Online exclusive
111.00 
Save 11.35 (10%)
-
Add to cart
Chemical Identifiers
CAS58109-40-3
IUPAC Namediphenyliodanium
Molecular FormulaC12H10I
InChI KeyOZLBDYMWFAHSOQ-UHFFFAOYSA-N
SMILES[I+](C1=CC=CC=C1)C1=CC=CC=C1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to pale cream
Melting Point (clear melt)138-145?C
FormCrystals or powder or crystalline powder
Elemental AnalysisCarbon: 32.98-34.67% (Theory: 33.83%)
Identification (FTIR)Conforms
Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

Solubility
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.

Notes
Light sensitive and hygroscopic. Incompatible with strong acids.
RUO – Research Use Only

General References:

  1. Cahard, E.; Male, H. P. J.; Tissot, M.; Gaunt, M. J. Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts. J. Am. Chem. Soc. 2015, 137 (25), 7986-7989.
  2. He, C.; Stoykovich, M. P. Photopatterning of Cross-Linkable Epoxide-Functionalized Block Copolymers and Dual-Tone Nanostructure Development for Fabrication Across the Nano-and Microscales. Small 2015, 11 (20), 2407-2416.