Sodium methoxide, ca 30% w/w in methanol is used in the preparation of high-spin hexanuclear Mn(III) cluster, [NaMn6 (OMe)12 (dbm)6]+. It is useful in the synthesis of pharmaceuticals and agrochemicals. It serves as an initiator of anionic addition polymerization with ethylene oxide, forming a polyether with high molecular weight.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Sodium methoxide, ca 30% w/w in methanol is used in the preparation of high-spin hexanuclear Mn(III) cluster, [NaMn6 (OMe)12 (dbm)6]+. It is useful in the synthesis of pharmaceuticals and agrochemicals. It serves as an initiator of anionic addition polymerization with ethylene oxide, forming a polyether with high molecular weight.
Solubility
Miscible with ethanol, fats and esters. Immiscible with hydrocarbons and organic solvents.
Notes
Air, moisture and heat sensitive. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents, alkali metals, chlorinated solvents, water and reducing agents.
RUO – Research Use Only
Tranchimand, S.; Faure, B.; Naubron, J. V.; Alphand, V.; Archelas, A.; Iacazio, G. Silica-Catalysed and Highly Stereoselective Convergent and Nonconvergent Rearrangements of Menthone Enol Acetate Epoxides: Easy Access to the Four α-Hydroxymenthone Stereoisomers. Eur. J. Org. Chem 2012, 2012, (23), 4365-4372.
Li, H. P.; Zhao, H. Preparing Biodiesel from High-acidity Waste Cooking Oil Catalyzed by Sodium Methoxide. Energy sourc. A, Recovery util. environ. effects 2015, 37 (3), 334-340.