Alkylation of [2,2?-([2,2?-bipyridine]-6,6?-diyl)bis[phenolato]-N,N?,O,O?]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.
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Applications
Alkylation of [2,2′-([2,2′-bipyridine]-6,6′-diyl)bis[phenolato]-N,N′,O,O′]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.
Solubility
Insoluble in water.
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light, bases.
RUO – Research Use Only
General References:
- Raess PW, et al. J. Catalytic reduction of 1-iodooctane by nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide: Effects of added proton donors and a mechanism involving both metal-and ligand-centered one-electron reduction of nickel (II) salen. Electroanal. Chem. 2007, 603 (1), 124-34.
- Danielle M Goken,; Dennis G Peters,; Jonathan A Karty,; James P Reilly. Alkylation of [2,2'-([2,2'-bipyridine]-6,6'-diyl)bis[phenolato]-N,N',O,O']nickel(II) during catalytic reduction of 1-iodooctane. Journal of Electroanalytical Chemistry. 2004, 564 123-132.