Thermo Scientific Chemicals

Ethyltriphenylphosphonium bromide, 98+%, Thermo Scientific Chemicals

Catalog number: B23096.36
500 g, Each
Thermo Scientific Chemicals

Ethyltriphenylphosphonium bromide, 98+%, Thermo Scientific Chemicals

Catalog number: B23096.36
500 g, Each
Quantity
Catalog number: B23096.36
also known as B23096-36
Price (USD)
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Chemical Identifiers

CAS
1530-32-1
IUPAC Name
ethyltriphenylphosphanium bromide
Molecular Formula
C20H20BrP
InChI Key
JHYNXXDQQHTCHJ-UHFFFAOYSA-M
SMILES
[Br-].CC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Appearance (Color)
White
Assay (Titration ex Bromide)
>98.0 to <102.0%
Water Content (Karl Fischer Titration)
<1.0%
Form
Crystalline powder

Description

Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination. It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions. Further, it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers and Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination. It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions. Further, it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers and Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

Solubility
Soluble in methanol. Slightly soluble in water, acetone and isopropanol.

Notes
Hygroscopic. Incompatible with oxidizing agents.
RUO – Research Use Only

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