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1-Formylpiperidine, 99%, Thermo Scientific Chemicals
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Catalog number B23452.0B
also known as B23452-0B
Price (USD)/ Each
323.00
-
Quantity:
1000 g
Price (USD)/ Each
323.00
1-Formylpiperidine, 99%, Thermo Scientific Chemicals
Catalog numberB23452.0B
Price (USD)/ Each
323.00
-
Chemical Identifiers
CAS2591-86-8
IUPAC Namepiperidine-1-carbaldehyde
Molecular FormulaC6H11NO
InChI KeyFEWLNYSYJNLUOO-UHFFFAOYSA-N
SMILESO=CN1CCCCC1
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Specifications
Specification Sheet
Specification SheetAppearance (Color)Clear colorless
Assay (GC)≥98.5%
Refractive Index1.4830-1.4860 @ 20?C
FormLiquid
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
Solubility
Freely soluble in water.
Notes
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
Solubility
Freely soluble in water.
Notes
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
RUO – Research Use Only
General References:
- Mary Jo Garber; Martha Gill; Yousheng Hua; Dennis Jenke. Development and Characterization of an LC-MS Method for Quantitating Aqueous Extractables, including Bisphenol A, 1 -Formylpiperidine, and Bis-(pentamethylene)-urea, from Plastic Materials. Journal of Chromatographic Science.2011, 49, (3), 214-220.
- Reaction with Grignard or alkyllithium reagents gives aldehydes in high yield: Angew. Chem. Int. Ed., 20, 878 (1981); Org. Synth. Coll., 7, 451 (1990).