Thermo Scientific Chemicals

Benzyltriphenylphosphonium bromide, 98%, Thermo Scientific Chemicals

Catalog number: B24567.30
250 g, Each
Thermo Scientific Chemicals

Benzyltriphenylphosphonium bromide, 98%, Thermo Scientific Chemicals

Catalog number: B24567.30
250 g, Each
Quantity
Catalog number: B24567.30
also known as B24567-30
Price (USD)
Quantity
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Chemical Identifiers

CAS
1449-46-3
IUPAC Name
benzyltriphenylphosphanium bromide
Molecular Formula
C25H22BrP
InChI Key
WTEPWWCRWNCUNA-UHFFFAOYSA-M
SMILES
[Br-].C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Form
Crystals or powder or crystalline powder
Water Content (Karl Fischer Titration)
≤2.0%
Appearance (Color)
White to pale cream
Identification (FTIR)
Conforms
Melting Point (clear melt)
292-299?C

Description

Benzyltriphenylphosphonium bromide is used as a reactant for stereoselective azidolysis of vinyl epoxides, enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine, biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A, enantioselective synthesis of syn-diarylheptanoids from D-glucose, preparation of β-amyloid plaque ligands and decarboxylative cyclopropanation. It react with 4-methyl-oxetan-2-one to produce 4-hydroxy-1-phenyl-1-(triphenyl-l5-phosphanylidene)-pentan-2-one.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Benzyltriphenylphosphonium bromide is used as a reactant for stereoselective azidolysis of vinyl epoxides, enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine, biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A, enantioselective synthesis of syn-diarylheptanoids from D-glucose, preparation of β-amyloid plaque ligands and decarboxylative cyclopropanation. It react with 4-methyl-oxetan-2-one to produce 4-hydroxy-1-phenyl-1-(triphenyl-l5-phosphanylidene)-pentan-2-one.

Solubility
Soluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
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