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m-Xylylene dibromide, 97%, Thermo Scientific Chemicals
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Catalog number B24959.30
also known as B24959-30
Price (USD)/ Each
1,049.00
-
Quantity:
250 g
Price (USD)/ Each
1,049.00
m-Xylylene dibromide, 97%, Thermo Scientific Chemicals
Catalog numberB24959.30
Price (USD)/ Each
1,049.00
-
Chemical Identifiers
CAS626-15-3
IUPAC Name1,3-bis(bromomethyl)benzene
Molecular FormulaC8H8Br2
InChI KeyOXHOPZLBSSTTBU-UHFFFAOYSA-N
SMILESBrCC1=CC(CBr)=CC=C1
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Specifications
Specification Sheet
Specification SheetAppearance (Color)White to cream to pale brown
FormCrystals or powder or crystalline powder
Assay (GC)≥96.0%
Melting Point (clear melt)71.0-81.0?C
It is used in preparation of four novel dinuclear half-titanocenes with meta- and orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is used in preparation of four novel dinuclear half-titanocenes with meta- and orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.
Solubility
Insoluble in water.
Notes
Store in a cool, dry conditions, in well sealed conditions. Store away from oxidizing agents, active metals, bases.
It is used in preparation of four novel dinuclear half-titanocenes with meta- and orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.
Solubility
Insoluble in water.
Notes
Store in a cool, dry conditions, in well sealed conditions. Store away from oxidizing agents, active metals, bases.
RUO – Research Use Only
General References:
- Murray V. Baker; David H. Brown; Valerie J. Hesler; Brian W. Skelton and Allan H. White. Synthesis of a Bis(N-heterocyclic carbene)palladium Complex via Oxidative Addition of a C-C Bond in a Biimidazolium Ion. Organometallics. 2007, 26 (2), 250-252.
- Keiiti Sisido; Nobuo Kusano; Ryôzi Noyori; Yôko Nozaki; Masatosi Simosaka and Hitosi Nozaki. Polycondensation of xylylene dibromides by transition metals in water suspension. Journal of Polymer Science Part A: General Papers. 1963, 1 (6), 2101-2107.
- Reductive coupling has been used in a relatively high-yielding route to [2,2]-m-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc. Perkin 1, 2029 (1991).