(R)-(+)-1,1'-Bi(2-naphthylamine) derivatives have been used for asymmetric hydrogenations, cyclopropanations and formation of chiral lactones. It can be used for the synthesis of sterically hindered binaphthalene-based monophosphane ligands.
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Applications
(R)-(+)-1,1′-Bi(2-naphthylamine) derivatives have been used for asymmetric hydrogenations, cyclopropanations and formation of chiral lactones. It can be used for the synthesis of sterically hindered binaphthalene-based monophosphane ligands.
Solubility
Slightly soluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible material is strong oxidizing agents.
RUO – Research Use Only
General References:
- Kurt Mislow; Paul Grasemann. Notes - Absolute Configuration of 1,1'-Bi-2-naphthylamine. J. Org. Chem. 1958, 23 (12), 2027-2028.
- Shane G. Telfer; Tomohiro Sato; Takunori Harada; Reiko Kuroda; Julie Lefebvre and Daniel B. Leznoff. Mono- and Dinuclear Complexes of Chiral Tri- and Tetradentate Schiff-Base Ligands Derived from 1,1‘-Binaphthyl-2,2‘-diamine. Inorg. Chem. 2004, 43 (20), 6168-6176.