Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.
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Applications
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.
Solubility
Reacts with water.
Notes
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.
RUO – Research Use Only
Hong Jin; Da-yu Wang; Yi-fang Mei; Wen-bing Qiu; Yi Zhou; Dong-ming Wang; Xue-rui Tan; Yu-guang Li. Mitogen-activated protein kinases pathway is involved in physiological testosterone-induced tissue factor pathway inhibitor expression in endothelial cells. Blood Coagulation and Fibrinolysis. 2010, 21 (5), 420-424.
R. Oost; J. Rong; A. J. Minnaard and S. R. Harutyunyan. Synthesis of new derivatives of copper complexes of Josiphos family ligands for applications in asymmetric catalysis. Catal. Sci. Technol. 2014, 4 (7), 1997-2005.