Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2?-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5?,6,6?,7,7?,8,8?-octahydro-1,1?-binaphthyl (Xyl-H 8 -BINAPO).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2′-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl (Xyl-H 8 -BINAPO).
Solubility
Reacts with water.
Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.
RUO – Research Use Only
Rongwei Guo,; Terry T.-L. Au-Yeung,; Jing Wu,; Michael C.K. Choi,;, Albert S.C. Chan. Modified BINAPO ligands for Rh-catalysed enantioselective hydrogenation of acetamidoacrylic acids and esters. Tetrahedron: Asymmetry. 2002, 13 (23), 2519-2522.