Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.
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Applications
Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.
Solubility
Reacts with water.
Notes
Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.
RUO – Research Use Only
General References:
- Chi-Feng Lin; Iwao Ojima. Formal enantioselective total synthesis of schulzeines A-C via Pd-catalyzed intramolecular asymmetric allylic amination. Journal of Organic Chemistry. 2011, 76 (15), 6240-6249.
- X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis(4-methoxyphenyl)phosphanyl]ferrocene. Acta Cryst. 2012, 68, 922.