(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%, Thermo Scientific Chemicals
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(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%, Thermo Scientific Chemicals

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Catalog number H25950.03
also known as H25950-03
Price (USD)/ Each
96.40
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Quantity:
1 g
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Price (USD)/ Each
96.40
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(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%, Thermo Scientific Chemicals
Catalog numberH25950.03
Price (USD)/ Each
96.40
-
Add to cart
Chemical Identifiers
CAS88335-93-7
SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to pale cream
FormCrystals or powder or crystalline powder
Assay (Aqueous acid-base Titration)≥97.5 to ≤102.5%
Water Content (Karl Fischer Titration)≤1.0%
Melting Point (clear melt)+11.5? ± 1.0? (c=1 in acetone)
(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester is used in organic synthesis as a starting material and intermediate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester is used in organic synthesis as a starting material and intermediate.

Solubility
Insoluble in water.

Notes
Incompatible with strong oxidizing agents, strong acid and bases.
RUO – Research Use Only

General References:

  1. Goswami, A.; Kissick, T. P. Enzymatic Desymmetrization of Dimethyl Cylcohex-4-ene-cis-1,2-dicarboxylate to (1S,2R)-2-(Methoxycarbonyl)cyclohex-4-ene-1-carboxylic Acid. Org. Process Res. Dev. 2009, 13 (3), 483-488.
  2. Solano, D. M.; Hoyos, P.; Hernáiz, M. J.; Alcántara, A. R.; Sánchez-Montero, J. M. Industrial biotransformations in the synthesis of building blocks leading to enantiopure drugs. Bioresour. Technol. 2012, 115, 196-207.
  3. Süss, P.; Illner, S.; von Langermann, J.; Borchert, S.; Bornscheuer, U. T.; Wardenga, R.; Kragl, U. Scale-Up of a Recombinant Pig Liver Esterase-Catalyzed Desymmetrization of Dimethyl Cyclohex-4-ene-cis-1,2-dicarboxylate. Org. Process Res. Dev. 2014, 18 (7), 897-903.