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4-(Ethoxycarbonyl)benzeneboronic acid, 94%, Thermo Scientific Chemicals
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Catalog number H26356.03
also known as H26356-03
Price (USD)/ Each
65.50
-
Quantity:
1 g
Price (USD)/ Each
65.50
4-(Ethoxycarbonyl)benzeneboronic acid, 94%, Thermo Scientific Chemicals
Catalog numberH26356.03
Price (USD)/ Each
65.50
-
Chemical Identifiers
CAS4334-88-7
IUPAC Name[4-(ethoxycarbonyl)phenyl]boronic acid
Molecular FormulaC9H11BO4
InChI KeyZLNFACCFYUFTLD-UHFFFAOYSA-N
SMILESCCOC(=O)C1=CC=C(C=C1)B(O)O
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Specifications
Specification Sheet
Specification SheetAppearance (Color)White
Assay (HPLC)≥92.0%
FormCrystals or powder or crystalline powder
Proton NMRConforms to structure
Assay (Aqueous acid-base Titration)≥92.0%
4-(Ethoxycarbonyl)benzeneboronic acid is used as a reactant involved in oxidative hydroxylation for the preparation of phenols, homolytic aromatic substitution, cross-coupling with α-bromocarbonyl compounds, Suzuki-coupling reaction with quinoline carboxylates, trifluoromethylation and carbometalation of ynamides.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-(Ethoxycarbonyl)benzeneboronic acid is used as a reactant involved in oxidative hydroxylation for the preparation of phenols, homolytic aromatic substitution, cross-coupling with α-bromocarbonyl compounds, Suzuki-coupling reaction with quinoline carboxylates, trifluoromethylation and carbometalation of ynamides.
Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
4-(Ethoxycarbonyl)benzeneboronic acid is used as a reactant involved in oxidative hydroxylation for the preparation of phenols, homolytic aromatic substitution, cross-coupling with α-bromocarbonyl compounds, Suzuki-coupling reaction with quinoline carboxylates, trifluoromethylation and carbometalation of ynamides.
Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- Nanase Uchiyama.; Eiji Shirakawa.; Ryo Nishikawa.; Tamio Hayashi. Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution. Chemical Communications. 2011, 47 (42), 11671-11673.
- Kiyofumi Inamoto.; Kanako Nozawa.; Misato Yonemoto.; Yoshinori Kondo. Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols. Chemical Communications. 2011, 47 (42), 11775-11777.