Diethyl acetylmethylphosphonate, 97%, Thermo Scientific Chemicals

Name: Diethyl acetylmethylphosphonate, 97%, Thermo Scientific Chemicals
SKU: H26896.06

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25 g

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Catalog number H26896.06

also known as H26896-06

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Quantity:

5 g

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Chemical Identifiers

CAS1067-71-6

IUPAC Namediethyl (2-oxopropyl)phosphonate

Molecular FormulaC7H15O4P

InChI KeyRSAFKRSMGOSHRK-UHFFFAOYSA-N

SMILESCCOP(=O)(CC(C)=O)OCC

Specifications

Specification Sheet

Appearance (Color)Clear colorless to pale yellow

FormLiquid

Assay (GC)≥96.0%

Refractive Index1.4315-1.4365 @ 20?C

Diethyl acetylmethylphosphonate is used as ligand in coordination chemistry to prepare lanthanide series metals like terbium, europium and neodymium.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diethyl acetylmethylphosphonate is used as ligand in coordination chemistry to prepare lanthanide series metals like terbium, europium and neodymium.

Solubility
Miscible with tetrahydrofuran, ether, dichloromethane and chloroform.

Notes
Incompatible with strong oxidizing agents.

RUO – Research Use Only

General References:

Iranpoor, N.; Firouzabadi, H.; Moghadam, K. R.; Davan, E. E. Triphenylphosphine/2, 3-Dichloro-5, 6-dicyanobenzoquinone (PPh₃/DDQ) System for Conversion of Alcohols and Thiols into Trialkyl Phosphonates. Asian J. Org. Chem. 2015, 4 (11), 1289-1293.
Xiong, F.; Wang, H.; Yan, L.; Xu, L.; Tao, Y.; Wu, Y.; Chen, F. Diastereoselective synthesis of pitavastatin calcium via bismuth-catalyzed two-component hemiacetal/oxa-Michael addition reaction. Org. Biomol. Chem. 2015, 13 (38), 9813-9819.