Thermo Scientific Chemicals

(S)-(-)-2-Methyl-2-propanesulfinamide, 97%, Thermo Scientific Chemicals

Catalog number: H27115.03
1 g, Each
Thermo Scientific Chemicals

(S)-(-)-2-Methyl-2-propanesulfinamide, 97%, Thermo Scientific Chemicals

Catalog number: H27115.03
1 g, Each
Quantity
Catalog number: H27115.03
also known as H27115-03
Price (USD)
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Chemical Identifiers

CAS
343338-28-3
IUPAC Name
2-methylpropane-2-sulfinamide
Molecular Formula
C4H11NOS
InChI Key
CESUXLKAADQNTB-UHFFFAOYNA-N
SMILES
CC(C)(C)S(N)=O
Appearance (Color)
White to pale cream or to pale yellow
Form
crystalline solid/powder
Assay (GC)
> 96.0%
Enantiomeric excess
>99.0%

Description

(S)-(-)-2-Methyl-2-propanesulfinamide is used in Suzuki reaction. It is also employed as a reagent for synthesizing chiral amines. It acts as a chiral auxiliary used in an asymmetric synthesis of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine. It is also involved in the transformation of P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins. Further, it serves as a reagent for the preparation of chemicals and pharmaceutical intermediates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(S)-(-)-2-Methyl-2-propanesulfinamide is used in Suzuki reaction. It is also employed as a reagent for synthesizing chiral amines. It acts as a chiral auxiliary used in an asymmetric synthesis of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine. It is also involved in the transformation of P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins. Further, it serves as a reagent for the preparation of chemicals and pharmaceutical intermediates.

Notes
Incompatible with strong oxidizing agents. Store in a cool place.
RUO – Research Use Only

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