Thermo Scientific Chemicals

Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF, Thermo Scientific Chemicals

Catalog number: H51156.AE
100 mL, Each
Thermo Scientific Chemicals

Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF, Thermo Scientific Chemicals

Catalog number: H51156.AE
100 mL, Each
Quantity
Catalog number: H51156.AE
also known as H51156-AE
Price (USD)
Quantity
-
Have Questions?

Chemical Identifiers

CAS
807329-97-1
IUPAC Name
lithium(1+) chloro(propan-2-yl)magnesium chloride
Molecular Formula
C3H7Cl2LiMg
InChI Key
CWTUREABAILGIK-UHFFFAOYSA-L
SMILES
[Li+].[Cl-].CC(C)[Mg]Cl
Assay (Titration)
0.8-1.2M

Description

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.
RUO – Research Use Only

Figures

Documents & Downloads

Certificates

    Frequently asked questions (FAQs)

    Citations & References

    Search citations by name, author, journal title or abstract text