3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. It also may be used in the synthesis of novel cyclic tetranuclear ZnII complex and synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. It also may be used in the synthesis of novel cyclic tetranuclear ZnII complex and synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.
Solubility
Slightly soluble in water.
Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- Xian-He Bu; Hiromasa Morishita; Kentaro Tanaka; Kumar Biradha; Sanae Furusho; Mitsuhiko Shionoya. A spontaneously resolved chiral molecular box: a cyclic tetranuclear ZnIIcomplex with DPTZ (DPTZ = 3,6-di-2-pyridyl-1,2,4,5-tetrazine) . Chem. Commun. 2000, (11),971-972
- Jiehu Cui; Liangfang Huang; Zhenzhong Lu; Yizhi Li; Zijian Guo; Hegen Zheng. Synthesis and properties of five unexpected copper complexes with ring-cleavage of 3,6-di-2-pyridyl-1,2,4,5-tetrazine by one pot in situ hydrothermal reaction. CrystEngComm. 2012, 14, (6),2258-2267