1-Ethynylcyclohexylamine was used in the synthesis of bicyclic and tetracyclic compounds. It was also used as a substrate in the reaction of a series of alkynes with mercury(II)acetate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Ethynylcyclohexylamine was used in the synthesis of bicyclic and tetracyclic compounds. It was also used as a substrate in the reaction of a series of alkynes with mercury(II)acetate.
Notes
Air sensitive. Incompatible with oxidizing agents and acids.
RUO – Research Use Only
General References:
- Mauro Bassetti; Barbara Floris. Metalation of alkynes. Part 2. Behaviour of alkynes with mercury(II) acetate in methanol: a systematic reinvestigation. J. Chem. Soc., Perkin Trans. 2. 1988, (2),227-233
- Antonio Arcadi; Sandro Cacchi; Giancarlo Fabrizi; Fabio Marinelli; Luca M.Parisi. Palladium-catalyzed reaction of aryl iodides with tertiarypropargylic amides.: Highly substituted allenes through a regioselective carbopalladation/β-N-Pd elimination reaction. Journal of Organometallic Chemistry. 2003, 687, (2),562-566