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4,5-Diazafluoren-9-one, 98%, Thermo Scientific Chemicals
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Catalog number H56028.03
also known as H56028-03
Price (USD)/ Each
115.65
Online exclusive
128.00 Save 12.35 (10%)
-
Quantity:
1 g
Price (USD)/ Each
115.65
Online exclusive
128.00 Save 12.35 (10%)
4,5-Diazafluoren-9-one, 98%, Thermo Scientific Chemicals
Catalog numberH56028.03
Price (USD)/ Each
115.65
Online exclusive
128.00 Save 12.35 (10%)
-
Chemical Identifiers
CAS50890-67-0
IUPAC Name3,13-diazatricyclo[7.4.0.0²,⁷]trideca-1(13),2,4,6,9,11-hexaen-8-one
Molecular FormulaC11H6N2O
InChI KeyPFMTUGNLBQSHQC-UHFFFAOYSA-N
SMILESO=C1C2=CC=CN=C2C2=NC=CC=C12
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Specifications
Specification Sheet
Specification SheetAssay (HPLC)>97.5%
4,5-Diazafluoren-9-one behaves like cyclopentadienones and reacts with [Cp*Co(C2H4)2] to form air -stable sandwich-type complexes [Cp*Co(η4-2)].
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4,5-Diazafluoren-9-one behaves like cyclopentadienones and reacts with [Cp*Co(C2H4)2] to form air -stable sandwich-type complexes [Cp*Co(η4-2)].
Solubility
Soluble in dichloromethane, tetrahydrofuran, chloroform, benzene, toluene and polar organic solvents. Insoluble in diethyl ether and alkanes.
Notes
Incompatible with strong oxidizing agents. Avoid heat and source of ignition.
4,5-Diazafluoren-9-one behaves like cyclopentadienones and reacts with [Cp*Co(C2H4)2] to form air -stable sandwich-type complexes [Cp*Co(η4-2)].
Solubility
Soluble in dichloromethane, tetrahydrofuran, chloroform, benzene, toluene and polar organic solvents. Insoluble in diethyl ether and alkanes.
Notes
Incompatible with strong oxidizing agents. Avoid heat and source of ignition.
RUO – Research Use Only
General References:
- Piotrowicz, M.; Zakrzewski, J.; Metivier, R.; Brosseau, A.; Makal, A.; Wozniak, K. Aerobic Palladium(II)-Catalyzed Dehydrogenative Heck Reaction in the Synthesis of Pyrenyl Fluorophores. A Photophysical Study of β-Pyrenyl Acrylates in Solution and in the Solid State. J. Org. Chem. 2015, 80 (5), 2573-2581.
- Liu, B.; Shi, B. Transition-metal-catalyzed etherification of unactivated C H bonds. Tetrahedron Lett. 2015, 56 (1), 15-22.