Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.
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Applications
Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.
Solubility
Miscible with ethanol, ethyl ether, benzene and organic solvents.
Notes
Moisture sensitive. Store in cool place. Incompatible with acids, bases and oxidizing agents.
RUO – Research Use Only
General References:
- Reaction with allyl bromide, mediated by In metal, affords diallylmethanol: Tetrahedron Lett., 44, 2911 (2003):
- Li, G.; Feng, X.; Du, H. Palladium-catalyzed asymmetric allylic amination of racemic butadiene monoxide with isatin derivatives. Org. Biomol. Chem. 2015, 13 (20), 5826-5830.
- Mao, W.; He, H. H.; Gu, J. Q.; Chen, W.; Wu, K.; Tok, E. S.; Xu, G. Q. Preservation of epoxy groups on surfaces in the covalent attachment of butadiene monoxide on Si(111)-(7x7): the effect of a vinyl substituent. Chem. Commun. 2015, 51 (75), 14195-14198.