Di-tert-butyl hydrazodicarboxylate, 98+%, Thermo Scientific Chemicals
Di-tert-butyl hydrazodicarboxylate, 98+%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Di-tert-butyl hydrazodicarboxylate, 98+%, Thermo Scientific Chemicals

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Quantity:
5 g
25 g
Catalog number L00280.06
also known as L00280-06
Price (USD)/ Each
64.80
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Quantity:
5 g
Request bulk or custom format
Price (USD)/ Each
64.80
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Di-tert-butyl hydrazodicarboxylate, 98+%, Thermo Scientific Chemicals
Catalog numberL00280.06
Price (USD)/ Each
64.80
-
Add to cart
Chemical Identifiers
CAS16466-61-8
IUPAC NameN'-[(tert-butoxy)carbonyl](tert-butoxy)carbohydrazide
Molecular FormulaC10H20N2O4
InChI KeyTYSZETYVESRFNT-UHFFFAOYSA-N
SMILESCC(C)(C)OC(=O)NNC(=O)OC(C)(C)C
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SpecificationsSpecification SheetSpecification Sheet
FormCrystals or powder or crystalline powder or fused solid
Appearance (Color)White
Assay (GC)≥98.0%
Di-tert-butyl hydrazodicarboxylate, is used as starting reagent during the four-step synthesis of the aminobicyclopyrazolone hydrochloride. It was used as reagent during Pd-catalyzed amination reactions of halo-pyridine substrates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Di-tert-butyl hydrazodicarboxylate, is used as starting reagent during the four-step synthesis of the aminobicyclopyrazolone hydrochloride. It was used as reagent during Pd-catalyzed amination reactions of halo-pyridine substrates.

Solubility
Insoluble in water.

Notes
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.
RUO – Research Use Only

General References:

  1. Paul Dowd.; Hermann Irngartinger. Tricyclo[2.1.0.02,5]pentane and its derivatives. Chem. Rev. 1989, 89, (5), 985-996.
  2. Paul. Dowd.; Wonghil. Chang.; Yi Hyon. Paik. Tetramethyleneethane, a ground-state triplet. J. Am. Chem. Soc. 1986, 108, (23), 7416-7417.
  3. Effective catalyst, in combination with CuCl : phenanthroline, for the aerobic oxidation of a variety of alcohols, aliphatic primary or secondary, benzylic or allylic to aldehydes or ketones. The method has potential as an ecologically benign process, since water is the only by-product: J. Org. Chem., 64, 2433 (1999):