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3-Hexyne, 99%, Thermo Scientific Chemicals
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Catalog number L02682.06
also known as L02682-06
Price (USD)/ Each
35.90
-
Quantity:
5 g
Price (USD)/ Each
35.90
3-Hexyne, 99%, Thermo Scientific Chemicals
Catalog numberL02682.06
Price (USD)/ Each
35.90
-
Chemical Identifiers
CAS928-49-4
IUPAC Namehex-3-yne
Molecular FormulaC6H10
InChI KeyDQQNMIPXXNPGCV-UHFFFAOYSA-N
SMILESCCC#CCC
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Specifications
Specification Sheet
Specification SheetAppearance (Color)Clear colorless to pale yellow
Assay (GC)≥98.5%
Identification (FTIR)Conforms
Refractive Index1.4095-1.4125 @ 20?C
FormLiquid
3-Hexyne is used in the synthesis of fused hetero-hydropyridyl ligands bonded to the {Ru(p-cymene)} organometallic moiety by reacting with ruthenacycles. It was also used in the preparation of [4+2] cycloaddition product by reacting with borole.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
3-Hexyne is used in the synthesis of fused hetero-hydropyridyl ligands bonded to the {Ru(p-cymene)} organometallic moiety by reacting with ruthenacycles. It was also used in the preparation of [4+2] cycloaddition product by reacting with borole.
Solubility
Not miscible in water.
Notes
Store away from oxidizing agents. Keep the container tightly closed in a cool, dry and well ventilated place.
3-Hexyne is used in the synthesis of fused hetero-hydropyridyl ligands bonded to the {Ru(p-cymene)} organometallic moiety by reacting with ruthenacycles. It was also used in the preparation of [4+2] cycloaddition product by reacting with borole.
Solubility
Not miscible in water.
Notes
Store away from oxidizing agents. Keep the container tightly closed in a cool, dry and well ventilated place.
RUO – Research Use Only
General References:
- Luciano Cuesta; Tatiana Soler; Esteban P Urriolabeitia. Cycloruthenated complexes from imine-based heterocycles: synthesis, characterization, and reactivity toward alkynes.Chemistry: A European Journal. 2012, 18,(47), 15178-15189.
- Fang Ge; Gerald Kehr; Constantin G Daniliuc; Gerhard Erker. Borole formation by 1,1-carboboration. Journal of the American Chemical Society. 2014, 136,(1), 68-71.
- On heating under pressure with norbornene and CO in the presence of Dodecacarbonyl triruthenium, 10507, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.