N,N,N',N'-Tetramethylmethylenediamine, 99%, Thermo Scientific Chemicals
Element SearchElement SearchStructure SearchStructure Search
N,N,N',N'-Tetramethylmethylenediamine, 99%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

N,N,N',N'-Tetramethylmethylenediamine, 99%, Thermo Scientific Chemicals

Have Questions?
Change viewbuttonViewtableView
Quantity:
25 g
100 g
ChemDexTry the chem dexTM web app
Catalog number L04037.14
also known as L04037-14
Price (USD)/ Each
59.30
-
Add to cart
Quantity:
25 g
Request bulk or custom format
Price (USD)/ Each
59.30
Add to cart
N,N,N',N'-Tetramethylmethylenediamine, 99%, Thermo Scientific Chemicals
Catalog numberL04037.14
Price (USD)/ Each
59.30
-
Add to cart
Chemical Identifiers
CAS51-80-9
SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Clear colorless
FormLiquid
Assay (GC)≥98.5%
Identification (FTIR)Conforms
Refractive Index1.3995-1.4025 @ 20?C
N,N,N',N'-Tetramethylmethylenediamine is a reagent used as a convenient source of the Mannich intermediate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
N,N,N′,N′-Tetramethylmethylenediamine is a reagent used as a convenient source of the Mannich intermediate.

Solubility
Fully miscible in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
RUO – Research Use Only

General References:

  1. Itaru Natori.; Shohei Inoue. Anionic Polymerization of 1,3-Cyclohexadiene with Alkyllithium/Amine Systems. Characteristics of n-Butyllithium,N,N‘,N‘-Tetramethylethylenediamine System for Living Anionic Polymerization. Macromolecules. 1998, 31 (15), 4687-4694.
  2. Wei-Guang Liu.; Siddharth Dasgupta.; Sergey V. Zybin.; William A. GoddardIII. First Principles Study of the Ignition Mechanism for Hypergolic Bipropellants: N,N,N',N'-Tetramethylethylenediamine (TMEDA) and N,N,N',N'-Tetramethylmethylenediamine (TMMDA) with Nitric Acid. J. Phys. Chem. A. 2011, 115 (20), 5221-5229.
  3. Has been used as a convenient source of the Mannich intermediate: J. Org. Chem., 33, 1719 (1968). For an example (dimethylaminomethyleneation of ferrocene), see: Org. Synth. Coll., 5, 434 (1973). Reaction with o-hydroxy ɑ-aryl acetophenones leads directly to isoflavanones: Synth. Commun., 29, 3895 (1999):
  4. Caution! The product of double lithiation has been reported to explode on drying: Org. Process Res. Dev., 7, 1029 (2003).