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1-(Triisopropylsilyl)pyrrole, 95%, Thermo Scientific Chemicals
Catalog number: L13152.14
25 g, Each
Thermo Scientific Chemicals
1-(Triisopropylsilyl)pyrrole, 95%, Thermo Scientific Chemicals
Catalog number: L13152.14
25 g, Each
Quantity
Catalog number: L13152.14
also known as L13152-14
Price (USD)
330.00
Each
Quantity
-
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Chemical Identifiers
CAS
87630-35-1
IUPAC Name
1-[tris(propan-2-yl)silyl]-1H-pyrrole
Molecular Formula
C13H25NSi
InChI Key
FBQURXLBJJNDBX-UHFFFAOYSA-N
SMILES
CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1
Specifications
Specification SheetAppearance (Color)
Clear colorless to yellow to green to brown
Form
Liquid
Refractive Index
1.4895-1.4955 @ 20?C
Assay (GC)
≥94.0%
Description
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
Solubility
Not miscible in water.
Notes
Moisture sensitive. Incompatible with oxidizing agents.
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
Solubility
Not miscible in water.
Notes
Moisture sensitive. Incompatible with oxidizing agents.
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