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(1S)-(-)-Camphanic chloride, 95%, Thermo Scientific Chemicals
Catalog number: L14148.03
1 g, Each
Thermo Scientific Chemicals
(1S)-(-)-Camphanic chloride, 95%, Thermo Scientific Chemicals
Catalog number: L14148.03
1 g, Each
Quantity
Catalog number: L14148.03
also known as L14148-03
Price (USD)
48.90
Each
Quantity
-
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Chemical Identifiers
CAS
39637-74-6
IUPAC Name
(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
Molecular Formula
C10H13ClO3
InChI Key
PAXWODJTHKJQDZ-VHSXEESVSA-N
SMILES
CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(Cl)=O
Specifications
Specification SheetAppearance (Color)
White to cream to grey
Form
Powder or crystals of flakes
Assay (Titration ex Chloride)
≥94.0 to ≤106.0%
Melting Point (clear melt)
64-71?C
Optical Rotation
-17? to -25? (c=3.5 in Chloroform)
Description
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol. Reacts with water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to moisture. Protect from humidity and water. Incompatible with bases and oxidizing agents.
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol. Reacts with water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to moisture. Protect from humidity and water. Incompatible with bases and oxidizing agents.
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