(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
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Applications
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol. Reacts with water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to moisture. Protect from humidity and water. Incompatible with bases and oxidizing agents.
RUO – Research Use Only
Demetrios N Nicolaides.; Daman R Gautam.; Konstantinos E Litinas.; Dimitra J Hadjipavlou-Litina.; Konstantina C Fylaktakidou. Synthesis and evaluation of the antioxidant and antiinflammatory activities of some benzo[l]khellactone derivatives and analogues. European Journal of Medicinal Chemistry. 2004, 39 (4 ), 323-332.
Andrew M. Riley.; H. Yasmin Godagea.; Mary F. Mahonb.; Barry V.L. Potter. Chiral desymmetrisation of myo-inositol 1,3,5-orthobenzoate gives rapid access to precursors for second messenger analogues. Tetrahedron: Asymmetry. 2006, 17 (2), 171-174.
Resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography: Helv. Chim. Acta, 51, 1587 (1968); 61, 2773 (1978).
Chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.